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Oxidized PAC-quinone imine metabolites have also been shown to form GSH-conjugates which inhibit glutathione reductase (GR): the decreased activity of GR hampers the detoxification and antioxidant capacity of the GSH-GSSG cycle, further aggravating the pro-oxidative status in the cell (Ndlov et al., 2014)
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The role of glutathione and glutathione S-transferases in mercapturic acid biosynthesis [PMID: 4892500] Laboratory literature summary: The role of glutathione and glutathione S-transferases in mercapturic acid biosynthesis
When bound to the tripeptide, coppers normally reactive properties become controlled, allowing safe delivery into cells without the oxidative damage that free copper ions would cause
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