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Molecular oxygen is a primary destabilizing factor for both senkyunolide A and I, with light and heat further promoting their breakdown under aerobic conditions (121)
The rationale is that effects accumulate during the course and persist between courses, with new courses reinforcing the previous effects
119 Conversely, at the N-terminal domain, a non-catalytic regulatory haem sensor negatively impacts the enzymatic activity of CBS upon reduction and completely inactivates the enzyme upon binding of nitric oxide or carbon monoxide
PROTAC-based therapies are also entering clinical development
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